2NaOH + CuSO4 → Cu(OH)2 + Na2SO4

n NaOH = 0,2.5 = 1(mol)

n CuSO4 = 0,1.2 = 0,2(mol)

Ta có :

n NaOH / 2 = 0,5 > n CuSO4 / 1 = 0,2 => NaOH dư

n Cu(OH)2 = n CuSO4 = 0,2 mol

=> m A = 0,2.98 = 19,6 gam

n Na2SO4 = n CuSO4 = 0,2 mol

n NaOH pư = 2n CuSO4 = 0,4(mol)

V dd = 0,2 + 0,1 = 0,3(lít)

Suy ra:

CM Na2SO4 = 0,2/0,3 = 0,67M

CM NaOH = (1 - 0,4)/0,3 = 2M

\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)

\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)

\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)

\(0.1.............0.05...............0.05...........0.05\)

\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)

\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)

\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)

n_Al = 5.4 / 27 = 0.2 (mol)

2Al + 6HCl => 2AlCl₃ + 3H₂

0.2......0.6............0.2.......0.3

a) V_H2 = 0.3 * 22.4 = 6.72 (l) 

b) m_AlCl3 = 0.2 * 133.5 = 26.7 (g) 

c) VddHCl = 0.6 / 1.5 = 0.4 (l) 

d) C_MAlCl3 = 0.2 / 0.4 = 0.5 (M) 

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)

\(n_{Na}=\dfrac{2,3}{23}=0,1\left(mol\right)\)

PTHH: 2Na + 2H₂O --> 2NaOH + H₂

            0,1-------------->0,1---->0,05

=> V_H2 = 0,05.22,4 = 1,12 (l)

m_{dd sau pư} = 2,3 + 197,8 - 0,05.2 = 200 (g)

=> \(C\%=\dfrac{0,1.40}{200}.100\%=2\%\)

\(V_{dd}=\dfrac{200}{1,08}=\dfrac{5000}{27}\left(ml\right)=\dfrac{5}{27}\left(l\right)\)

=> \(C_M=\dfrac{0,1}{\dfrac{5}{27}}=0,54M\)

nNaOH = 4/40 = 0.1 (mol)

PTHH: NaOH + HCl -> NaCl + H2O

Từ PTHH: nNaCl = nHCl = nNaOH = 0.1 (mol)

a) mNaCl = 0.1*(23+35.5) = 5.85(g)

b) mHCl = 0.1*(1+35.5) = 3.65(g)

C%ddHCl = 3.65/100 * 100% = 3.65%

Bài 9 : 

\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

0,05--->0,1-------->0,05 

a) \(C_{MddHCl}=\dfrac{0,1}{0,1}=1\left(M\right)\)

b) \(m_{CuCl2}=0,05.135=6,75\left(g\right)\)

c) \(C_{MCuCl2}=\dfrac{0,05}{0,1}0,5\left(M\right)\)

Câu 10 : 

\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)

\(FeO+2HCl\rightarrow FeCl_2+H_2O\)

0,05-->0,1------->0,05

\(m_{ddHCl}=\dfrac{0,1.36,5}{10\%}100\%=36,5\left(g\right)\)

\(m_{ddspu}=3,6+36,5=40,1\left(g\right)\)

\(C\%_{FeCl2}=\dfrac{0,05.127}{40,1}.100\%=15,84\%\)

Câu 10 :

\(n_{FeO}=\dfrac{3,6}{72}=0,05\left(mol\right)\)

PTHH :

\(FeO+2HCl\rightarrow FeCl_2+H_2O\)

0,05      0,1           0,05       0,05

\(m_{ddHCl}=\dfrac{0,1.36,5.100}{10}=36,5\left(g\right)\)

\(C\%_{FeCl_2}=\dfrac{0,05.127}{\left(3,6+36,5\right)}.100\%=15,84\%\)

200ml = 0,2l

\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)

Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)

        1         2              1           1

     0,3      0,6             0,3        0,3

a) \(n_{ZnCl2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)

\(C_{M_{ZnCl2}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)

b) \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)

\(V_{H2\left(dktc\right)}=0,3.22,4=6,72\left(l\right)\)

c) Pt : \(NaOH+HCl\rightarrow NaCl+H_2O|\)

              1            1              1            1

            0,6          0,6

\(n_{NaOH}=\dfrac{0,6.1}{1}=0,6\left(mol\right)\)

\(m_{NaOH}=0,6.40=24\left(g\right)\)
\(m_{ddNaOH}=\dfrac{24.100}{20}=120\left(g\right)\)

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